3,3′-{Ethane-1,2-diylbis[carbonylbis(azanediyl)]}dipyridinium tetrachloridoplatinate(II)
نویسندگان
چکیده
In the crystal structure of the title compound, (C(14)H(18)N(6)O(2))·[PtCl(4)], the cation and square-planar anion are located on special positions (on a twofold axis and an inversion centre, respectively). In the crystal structure, N-H⋯Cl hydrogen bonds lead to a staircase-like motif. The central ethane backbone of the cation is disordered over two positions of equal occupancy.
منابع مشابه
Tetraaquatetrakis{μ3-3,3′-[(E,E)-ethane-1,2-diylbis(nitrilomethylidyne)]benzene-1,2-diolato}octazinc(II) N,N-dimethylformamide hexasolvate
The asymmetric unit of the title compound [Zn(8)(C(16)H(12)N(2)O(4))(4)(H(2)O)(4)]·6C(3)H(7)NO, consists of eight Zn(II) cations, four tetra-valent anionic ligands, L(4-) (L(4-) = 3,3'-(1E,1'E)-(ethane-1,2-diylbis(azan-1-yl-1-yl-idene))bis-(methan-1-yl-1-yl-idene)dibenzene-1,2-bis-(olate), four coordinated water mol-ecules and six N,N-dimethyl-formamide solvate mol-ecules. The coordination comp...
متن کامل(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN 4)bis(nitrato-κO)nickel(II) monohydrate
In the title complex, [Ni(NO3)2(C14H16N6O2)]·H2O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetra-dentate 3,3'-{(1E,1'E)-1,1'-[ethane-1,2-diylbis(azan-1-yl-1-yl-idene)]bis-(ethan-1-yl-1-yl-idene)}di-pyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted o-cta-hedral geometry. The lattice water mol-ecule is located on a twofold rotat...
متن کاملcatena-Poly[1,1′-dimethyl-4,4′-(ethane-1,2-diyl)dipyridinium [lead(II)-tri-μ-iodido-lead(II)-tri-μ-iodido]]
The title compound, {(C(14)H(18)N(2))[Pb(2)I(6)]}(n), consists of discrete 1,1'-dimethyl-4,4'-(ethane-1,2-di-yl)dipyridinium cations and one-dimensional [Pb(2)I(6)](n) anions. The organic cation has an inversion center at the mid-point of the ethane C-C bond. In the anion, the Pb(II) atom is coordinated by six I atoms in a distorted octa-hedral geometry. The I atoms bridge the Pb(II) atoms into...
متن کامل1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) as an organocatalyst for the silylation/desilylation reaction
1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) was used as a chemoselective and effective organocatalyst for the silylation of hydroxyl groups as well as desilylation of trimethylsilyl ethers under mild conditions at room temperature with good to excellent yields.
متن کامل1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) as an organocatalyst for the silylation/desilylation reaction
1,1’-(Ethane-1,2-diyl)dipyridinium bistribromide (EDPBT) was used as a chemoselective and effective organocatalyst for the silylation of hydroxyl groups as well as desilylation of trimethylsilyl ethers under mild conditions at room temperature with good to excellent yields.
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